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An Efficient Diastereoselective Glyoxylate-ene Reaction Using N-Glyoxyloyl Camphorpyrazolidinone as an Enophile.

✍ Scribed by Jia-Fu Pan; Uppala Venkatesham; Kwunmin Chen

Book ID
101971335
Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Deju Shang; Yanling Liu; Xin Zhou; Xiaohua Liu; Xiaoming Feng 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB 👁 2 views

## Abstract **Mild mannered!** A highly diastereo‐ and enantioselective Mannich‐type reaction of glycine Schiff base **1** has been developed by using the __N,N′__‐dioxide **L**‐Cu^II^ complex as a catalyst. Various optically active __anti‐__α,β‐diamino acid esters were obtained in good yields with