An efficient chemo and regioselective oxidative nuclear bromination of activated aromatic compounds using lithium bromide and ceric ammonium nitrate
โ Scribed by Subhas Chandra Roy; Chandrani Guin; Kalyan Kumar Rana; Gourhari Maiti
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- French
- Weight
- 71 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
A mild, efficient and highly chemo-and regioselective method for the bromination of electron rich aromatic molecules has been developed by electrophilic substitution of Br + , which was generated in situ from LiBr using ceric ammonium nitrate as the oxidant. Free aromatic amines remained unaffected under the reaction conditions.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
A mild and efficient ecofriendly method for the halodecarboxylation of a,b-unsaturated aromatic acids has been developed by using lithium bromide/chloride and ceric ammonium nitrate in acetonitrile-water at room temperature to afford the vinyl halides in moderate to good yields.