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An efficient approach towards three component coupling of one pot reaction for synthesis of functionalized benzopyrans

โœ Scribed by B. Sunil Kumar; N. Srinivasulu; R. H. Udupi; B. Rajitha; Y. Thirupathi Reddy; P. Narsimha Reddy; P. S. Kumar


Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
153 KB
Volume
43
Category
Article
ISSN
0022-152X

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โœฆ Synopsis


Abstract

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Three component coupling of one pot reaction which servers as the most convenient route to the synthesis of benzopyran derivatives using the TiCl~4~ catalyst (10 mol %) under solvent free conditions is described. The procedure offers a systematic method with a number of advantages including operational simplicity, neat reactions, reduced reaction time, high yields of products and applicability to large scale reactions.


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A One-Pot Cross-Metathesis/Allylboration
โœ Steven D. Goldberg; Robert H. Grubbs ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 87 KB ๐Ÿ‘ 2 views

General procedure: A flame-dried round-bottomed flask was charged with 4 (1 equiv) and the olefin cross partner (3.0 equiv). A rubber septum was attached, dichloromethane was added (0.2 ยฑ 0.3 n in 4), and argon was bubbled through the resultant solution for 10 min. Under a stream of argon, 3 (0.050