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An Efficient and Stable Ionic Liquid System for Synthesis of Ethylene Glycol via Hydrolysis of Ethylene Carbonate

✍ Scribed by Zhenying MENG; Jian SUN; Jinquan WANG; Jianxin ZHANG; Zengzeng FU; Weiguo CHENG; Xiangping ZHANG

Book ID
114338415
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
270 KB
Volume
18
Category
Article
ISSN
1004-9541

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Transesterification of urea and ethylene
Transesterification of urea and ethylene glycol to ethylene carbonate as an important step for urea based dimethyl carbonate synthesis
✍ Bhanage, Bhalchandra M.; Fujita, Shin-ichiro; Ikushima, Yutaka; Arai, Masahiko πŸ“‚ Article πŸ“… 2003 πŸ› Royal Society of Chemistry 🌐 English βš– 86 KB

Two-step synthesis of dimethyl carbonate (DMC) from urea has been investigated with various solid catalysts. The first step involves reaction of urea with ethylene glycol (EG) to form ethylene carbonate (EC) and the second step transesterification of EC formed with methanol to give DMC and EG. It ha