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An efficient and short degradation of the cholic acid side chain: a new method for the preparation and dehydrogenation of 4,5-dihydro-oxazoles

✍ Scribed by Barton, Derek H. R.; Motherwell, William B.; Wozniak, Jocelyne; Zard, Samir Z.


Book ID
120901866
Publisher
Royal Society of Chemistry
Year
1985
Weight
609 KB
Category
Article
ISSN
1472-7781

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Photochemische Reaktionen. 92. Mitteilun
✍ Shigeo Iwasaki πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 728 KB

## Abstract Irradiation of N‐stearoylimidazole (**1**) gave hexadec‐1‐ene (**4**) in 45% yield, whereas irradiation of N‐(4‐methylstearoyl)imidazole (**13**) possessing a tertiary hydrogen atom Ξ³ to the carbonyl group led to 2‐methylhexadec‐1‐ene (**14**) in 62% yield. These results are explained b