✦ LIBER ✦

An efficient and mild ruthenium-catalyzed racemization of amines: application to the synthesis of enantiomerically pure amines

✍ Scribed by Oscar Pàmies; Alida H. Éll; Joseph S.M. Samec; Nina Hermanns; Jan-E. Bäckvall

Book ID: 104251235
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 105 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00817-1

No coin nor oath required. For personal study only.

✦ Synopsis

An efficient and mild Ru-catalyzed racemization of amines under transfer hydrogenation conditions is reported. A significant advantage of this new procedure is that the ruthenium hydrogen transfer catalysts allow high functional group tolerance. Interestingly, both primary and secondary amines were efficiently racemized under these conditions. We also report on the combination of this new amine racemization with an enzymatic kinetic resolution of primary amines.

📜 SIMILAR VOLUMES

An Efficient and Mild Ruthenium-Catalyze

An Efficient and Mild Ruthenium-Catalyzed Racemization of Amines: Application to the Synthesis of Enantiomerically Pure Amines.

✍ Oscar Pamies; Alida H. Ell; Joseph S. M. Samec; Nina Hermanns; Jan-E. Baeckvall 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

An Efficient and General Synthesis of Pr

An Efficient and General Synthesis of Primary Amines by Ruthenium-Catalyzed Amination of Secondary Alcohols with Ammonia

✍ Sebastian Imm; Sebastian Bähn; Lorenz Neubert; Dr. Helfried Neumann; Prof. Dr. M 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 350 KB 👁 2 views

ChemInform Abstract: An Efficient and Ge

ChemInform Abstract: An Efficient and General Synthesis of Primary Amines by Ruthenium-Catalyzed Amination of Secondary Alcohols with Ammonia.

✍ Sebastian Imm; Sebastian Baehn; Lorenz Neubert; Helfried Neumann; Matthias Belle 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 38 KB 👁 2 views

An Efficient Conversion of Chiral α-Amin

An Efficient Conversion of Chiral α-Amino Acids to Enantiomerically Pure 3-Amino Cyclic Amines

✍ Moon, Sung-Hwan; Lee, Sujin 📂 Article 📅 1998 🏛 Taylor and Francis Group 🌐 English ⚖ 296 KB

A Chemoenzymatic Approach to Enantiomeri

A Chemoenzymatic Approach to Enantiomerically Pure Amines Using Dynamic Kinetic Resolution: Application to the Synthesis of Norsertraline

✍ Lisa K. Thalén; Dongbo Zhao; Jean-Baptiste Sortais; Jens Paetzold; Christine Hob 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 447 KB 👁 2 views

ChemInform Abstract: Synthesis of the No

ChemInform Abstract: Synthesis of the Novel Amine (R*,R*,R*)-Tris-(α-methylbenzyl)amine. X-Ray Crystal Structures of Racemic and Enantiomerically Pure Forms.

✍ Paul Wyatt; Craig P. Butts; Vipulkumar Patel; Ben Voysey 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v