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An efficient and highly selective cleavage of N-tert-butoxycarbonyl group under microwave irradiation

โœ Scribed by D.Subhas Bose; V. Lakshminarayana


Book ID
104259566
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
188 KB
Volume
39
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


A simple and high yielding method for the cleavage of t-Boc carbamates is described which occurs under mild and solvent-free conditions using microwave irradiation.


๐Ÿ“œ SIMILAR VOLUMES


Rapid N-tert-butoxycarbonylation of amin
โœ N. Suryakiran; P. Prabhakar; T. Srikanth Reddy; M. Srinivasulu; N. Raghavendra S ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 166 KB

Rapid N-tert-butoxycarbonylation of amines by treatment with di-tert-butyl dicarbonate in the presence catalytic amount of Bi(NO 3 ) 3 โ€ข5H 2 O as a mild and highly efficient catalyst under solvent-free conditions at room temperature in excellent yields is described.