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An efficient 1,3-asymmetric induction accompanied with epimerization at the 2-position. Stereoselective reduction of α-substituted β-keto sulfoxides under basic conditions

✍ Scribed by Katsuyuki Ogura; Makoto Fujita; Takashi Inaba; Kazumasa Takahashi; Hirotada Iida


Book ID
104216952
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
291 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


An efficient 1,3-asymetric induction was realized in the reduction of B-keto sutfoxides having various a-substituents with NaBH, under basic conditions and, by the appzication of this induction, CR)-+acetoxyphenyZacetaZdehyde was synthesized.