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An Effective System to Synthesize Methanofullerenes: Substrate—Ionic Liquid—Ultrasonic Irradiation.

✍ Scribed by Zhu Yinghuai; Stefan Bahnmueller; Ching Chibun; Keith Carpenter; Narayan S. Hosmane; John A. Maguire

Book ID
101944893
Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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An effective system to synthesize methan
An effective system to synthesize methanofullerenes: substrate–ionic liquid–ultrasonic irradiation
✍ Zhu Yinghuai; Stefan Bahnmueller; Ching Chibun; Keith Carpenter; Narayan S. Hosm 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 109 KB

Dehalogenation of the polyhalides, CHCl 3 , C 60 (CCl 2 ), CH 2 I 2 , and 7,7-dibromobicyclo(4,1,0)heptane, by treatment with zinc, magnesium or NaOH powder, followed by the in situ reaction with fullerene in the presence of ultrasonic irradiation and in the ionic liquid solvents, [bmim][PF 4 ] or [