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An effective extension of the polyacetate chain in the polyene macrolide antibiotic filipin III, based on chiral oxazaborolidinone-promoted asymmetric aldol reactions

✍ Scribed by Syun-ichi Kiyooka; Mostofa A Hena; Tomomi Yabukami; Kazunori Murai; Fumitaka Goto


Book ID
104210841
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
190 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


The enantioselective construction of the iterative polyacetate unit 3 in filipin III has been accomplished, essentially by an aldol strategy based on chiral oxazaborolidinone-promoted asymmetric aldol reactions.