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An Effective Approach to Layered Structures of Hybrid Prussian Blue Complexes: Monolayered [Sm(DMF) 2 (H 2 O) 3 (μ-CN) 3 M(CN) 3 ] n · n H 2 O and Bilayered [Sm(DMF)(H 2 O) 3 (μ-CN) 4 M(CN) 2 ] n · n H 2 O (M = Fe, Co)

✍ Scribed by Chen, Wen-Tong; Wang, Ming-Sheng; Cai, Li-Zhen; Xu, Gang; Akitsu, Takashiro; Akita-Tanaka, Motoko; Guo, ; Huang, Jin-Shun


Book ID
126923506
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
166 KB
Volume
6
Category
Article
ISSN
1528-7483

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Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ‫؍‬ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]