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An automated titration of phosphine and a first investigation of the application in the determination of organo-phosphorus compounds

✍ Scribed by F. G. Römer; A. J. H. Schimmelpenninck van der Oije; B. Griepink


Book ID
105113637
Publisher
Springer
Year
1978
Tongue
English
Weight
258 KB
Volume
69
Category
Article
ISSN
0026-3672

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The dependencies of Ka line shifts of the P and S atoms on effective charges of the atoms, calculated by CNDO/S, CNDOIZ, INDO, and MNDO methods in the minimal and extended basis sets, have been investigated for model compounds. Good linear relationships between Ka shifts and atomic charges have been