An Asymmetric, Chemoenzymatic Synthesis of O-Acetylcyanohydrins.
β Scribed by Yuri N. Belokon; A. John Blacker; Lisa A. Clutterbuck; David Hogg; Michael North; Christopher Reeve
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 31 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Almond β€-glucosidase was used to catalyze the synthesis of alkyl β€-Dglucopyranosides 1b-3b starting from either D-glucose (4) or phenyl-β€-Dglucopyranoside (5) and the racemic alcohols 1a-3a. The enzymic reactions were provided in different acetonitrile/water mixtures [9:1 (v/v) for the reverse hydro