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An Assessment of Theoretical Procedures for Predicting the Thermochemistry and Kinetics of Hydrogen Abstraction by Methyl Radical from Benzene

✍ Scribed by Hemelsoet, Karen; Moran, Damian; Van Speybroeck, Veronique; Waroquier, Michel; Radom, Leo


Book ID
111937769
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
204 KB
Volume
110
Category
Article
ISSN
1089-5639

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Measurements rate constants for abstraction of hydrogen from ethylene by methyl and ethyl radicals relative to the corresponding rate constants for abstraction from hydrogen, over the temperature range 650-770 K, are reported. The method is based on the effect of the addition of small quantities of