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An assessment of the dual capacitor model for the metal—electrolyte double layer

✍ Scribed by I.L. Cooper; J.A. Harrison

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
704 KB
Volume
22
Category
Article
ISSN
0013-4686

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✦ Synopsis

The long-accepted subdivision of the double layer at the metatelectrolyte interface into compact and diffuse region% resulting in Grahame's construction of a concentration-independent compact layer capacity, is shown to be a consequence of certain unreasonable assumptions and approximations. Theoretical treatments of the double layer involving the orientational behaviour of a layer of water molecules between a charged metal surface and a layer of charge at the outer Helmholtz plane are shown to be quite unrealistic.

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