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An “Aprotic” Tamao Oxidation/ Syn -Selective Tautomerization Reaction for the Efficient Synthesis of the C(1)–C(9) Fragment of Fludelone

✍ Scribed by Harrison, Tyler J.; Rabbat, Philippe M. A.; Leighton, James L.


Book ID
118058721
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
385 KB
Volume
14
Category
Article
ISSN
1523-7060

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ChemInform Abstract: A Scalemic Synthesi
✍ J. R. TAGAT; S. W. MCCOMBIE; M. S. PUAR 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 2 views

Starting with the known ester (I) derived from abietic acid only a trace of the desired title skeleton (XIII) is obtained. It is noteworthy that the aldehyde (VII) under basic or acidic conditions gives exclusively the undesired compound (VIII). -(TAGAT, J.