An approximate calculation of the thermal expansion of solids I
β Scribed by M.J. Druyvesteyn; J.L. Meyering
- Publisher
- Elsevier Science
- Year
- 1941
- Weight
- 393 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0031-8914
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β¦ Synopsis
Zusammenfassung
Der Ausdehnungskoeffizient eines festen K6rpers ist annghernd dem dritten Differentialquotienten der Gitterenergie nach der L~nge propor. tional. Der Ausdehnungskoeffizient wird ffir die Alkalimetalle berechnet und in guter Obereinstimmung mit den experimentellen Werten befun-
π SIMILAR VOLUMES
It is pointed out that the thermal expansion coefficient of solids is not always zero even in ideally harmonic crystals, if one quantizes the phonon field. This apparently differs from the customary treatment which is essentially based on non-quantized phonon field model. Our discussion which starts
A parameter-free model based on molecular mechanics with zero Kelvin potentials is developed to describe quantitatively the shortening of the unit cell of polyethylene crystals in chain direction with increasing temperature. Based on the well-known conception that an increase of the amplitudes of th