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An approach to the stereocontrolled synthesis of polysubstituted chiral butenolides and γ-lactones

✍ Scribed by Carmen Ma Rodríguez; Victor S. Martín


Book ID
104212855
Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
214 KB
Volume
32
Category
Article
ISSN
0040-4039

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Stereocontrolled approach to δ- and γ-la
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Two complementary approaches have been realized for the stereoselective synthesis of 4,6-disubstituted d-lactones and 1,3-anti and syn diols. In the 6-endo selenolactonization the role of the X -ion on the stereoselectivity is shown. Moreover, the highly stereoselective transformation of the 6-endo