An application of the thermal desorption method to the surface characterization of RuO2IrO2 and RuO2TiO2 coated titanium electrodes
✍ Scribed by Yoshio Takasu; Kohji Tsukada; Katsunori Nishimura; Tadao Hiromine; Kiyochika Yahikozawa
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 269 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
Abdrac-Thermal desorption spectrometry of CO was applied to surface analysis of RuOs-IrO, and RuOs-Tii, coated titanium electrodes. Content of RuO, at the surface of the former electrodes was the same as in the bulk, whereas the surface of the latter ones was enriched in TiO, to a significant extent. Furthermore, some alloying et%& between RuO, and TiO, or IrO, were observed. These results were supported by means of cyclic voltammetry.
📜 SIMILAR VOLUMES
High-dose gamma irradiation of electrodes provided with an active film consisting of 5 mol. % RuO, and 95 mol. y0 TiO, may produce electrodes whose chlorine overvoltage at 60°C in a solution containing 3COg NaCl per dm' conforms to the relation r/ = 0.44 + 0.190. log i (V; A/cm\*) for i e (0.04; 1.5