An Application of Borane As a Protecting Group for Pyridine
β Scribed by Zajac, Matthew A.
- Book ID
- 121416115
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 226 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0022-3263
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In the course of studies directed towards the total synthesis of trichodermin 1 and trichothecolone 2 we required the a,B-unsaturated Ketones 1 and Q,and the cis-ketol 1 2. We wish to report, first,the preparation of the diketoethers 5 and 1 and their cyclization to give 2 and 4\_, respectively. Bot