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An anomalous mannich reaction of a trimethylsilyl enol ether

✍ Scribed by Samuel Danishefsky; Michael Kahn; Michael Silvestri

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 174 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)87122-1

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✦ Synopsis

Mannich reaction between dimethyl (methylene) ammonium chloride and a silyl enol ether gives a regiochemical result opposite to that obtained from the derived lithium enolate and the same salt.

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