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An Anomalous Houben—Hoesch Reaction and Some Applications in Arylation Reactions.

✍ Scribed by F. Sanchez-Viesca; Maria R. Gomez; Martha Berros

Publisher
John Wiley and Sons
Year
2004
Weight
118 KB
Volume
35
Category
Article
ISSN
0931-7597

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2-Amino-4-methyloxazole gives 5-substituted products when treated with aldehydes instead of expected Schiff bases. Reactions of aldehydes and amines, including heterocyclic amines, are generally straight forward and give the expected imines or Schiff bases1'2'3. However, when an equimolar ratio of 2