An anomalous course of the reduction of 2-(3-oxo-3,4-dihydro-quinoxalin-2-yl)benzene diazonium salt. Synthesis of a new quinoxalino[1,2-c][1,2,3]benzotriazine system
✍ Scribed by Iveta Wiedermannová; Jan Slouka; Otakar Humpa; Karel Lemr
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2003
- Tongue
- English
- Weight
- 27 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
By diazotization of 3‐(2‐aminophenyl)quinoxaline‐2(l__H__)‐one la and 3‐(2‐aminophenyl)‐6,7‐dimethylquinoxaline‐2(l__H__)‐one 1b followed by the reaction with sodium sulphite new quinoxalino[1,2‐c]‐[1,2,3]benzotriazins 4a and 4b were prepared, respectively.
📜 SIMILAR VOLUMES
## Abstract The ^1^H,^13^C and ^15^N NMR spectra of the reduction product of 2‐(3‐oxo‐3,4‐dihydroquinoxalin‐2‐yl)benzene diazonium salt with sodium sulfite were measured and analysed. It is shown that the reaction product corresponds to 1‐(indazol‐3‐yl)‐1,2‐dihydro‐benzimidazol‐2‐on and not 6__H__‐
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## Abstract magnified image Reaction of isatoic anhydride with an alkanediamine in DMF solution under mild conditions affords excellent yields of the 1,__x__‐bis‐{(2‐aminobenzoyl‐)amino}alkanes (**2a‐k**), which have been characterized by IR and NMR spectroscopy, high resolution mass spectrometry
## Abstract 3‐Benzylindole‐2‐carbohydrazides (4) on reaction with triethylorthoformate in a polar solvent like DMF yielded only 10‐benzyl‐1,2‐dihydro‐1‐oxo‐1,2,4‐triazino[4,5‐__a__]indoles (5) while (4) on reaction with triethylorthoacetate in DMF yielded both 10‐benzyl‐4‐methyl‐1,2‐dihydro‐1‐oxo‐1