An Anionic Mn(III) Ethyleneglycolate Complex
β Scribed by Ulrich Schubert; Kurt Mereiter; Ines Elhofer
- Book ID
- 106214838
- Publisher
- Springer Vienna
- Year
- 2000
- Tongue
- English
- Weight
- 156 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0026-9247
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π SIMILAR VOLUMES
Acylation of alcohols in an efficient manner using [N,N -ethylene bis(salicylideneaminato)] manganese(III) chloride [Mn(III) salen complex 1] with anhydrides/acetic acid under novel heterogeneous media is reported for the first time.
Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an