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An Anhydro Derivative of D-Mannosan β (presumably 3,4-Anhydro-D-talosan β)

✍ Scribed by Hann, Raymond M.; Hudson, C. S.


Book ID
120405668
Publisher
American Chemical Society
Year
1942
Tongue
English
Weight
479 KB
Volume
64
Category
Article
ISSN
0002-7863

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A novel route to 1,4-anhydro derivatives
✍ Clive Bullock; Leslie Hough; Anthony C. Richardson 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 604 KB

Treatment of 1-0-acetyl-4-0-mesyl derivatives of a-o-glucopyranose with sodium azide in N,N-dimethylformamide gave 1,4-anhydro derivatives of P-D- galactopyranose and not the expected 4-azides. 1,4-Anhydro-6-azido-2,3-di-Obenzoyl-6-deoxy+-D-galactopyranose was converted into the corresponding 6bromi