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An analytical solution for the kinetics of AB(1k,1ϕ) systems and its application to a spirobenzopyran

✍ Scribed by M. Maafi; R. G. Brown

Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 181 KB
Volume: 39
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.20267

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✦ Synopsis

Abstract

A new, rapid method is described which determines the absolute values of all the unknown parameters of an AB(1__k__,1ϕ) reactive system from experimental information about the change of absorbance with time at any given wavelength. The mathematical algorithm is given for the case where the spectrum of the isomer B is not experimentally accessible and overlaps the spectrum of A. An example of its application to a photochromic spiropyran derivative is given. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 539–545, 2007

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