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An analytical method for the calculation of the relative intensities of bending and stretching modes in inelastic neutron scattering spectra

✍ Scribed by Joseph Howard; John Tomkinson


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
228 KB
Volume
98
Category
Article
ISSN
0009-2614

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✦ Synopsis


An approximate analytical method is presented for calculating the relative intensities of the bands due to the stretching (v) and doubly degenerate bending (S) modes of species such as M-H-M

or XsC-H in their inelastic neutron scattering spectra. For data collected using a beryllium filter detector spectrometer it is shown that, provided the two bands are not at opposite ends of the appropriate wavenumber range (500-3500 c&l), this method is in excellent agreement with exact Calculations based on a numerical orientational averaging technique. The method is illustrated with data for NaHF2.