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An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates

✍ Scribed by John P Wolfe; Jens Åhman; Joseph P Sadighi; Robert A Singer; Stephen L Buchwald

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
435 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

C b a e p c h h h a @1997 E1sevier Science Ltd. A p n b c i t f c d p p s u d c b a c b a c a s ' ,Phgh catalytic amination "o R,, \

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2-(Trimethylsilyl)ethanesulfonyl amide a
2-(Trimethylsilyl)ethanesulfonyl amide as a new ammonia equivalent for palladium-catalyzed amination of aryl halides
✍ Prakash Anjanappa; Dibakar Mullick; Kumaravel Selvakumar; Manickam Sivakumar 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 201 KB

Trimethylsilyl)ethanesulfonyl amide a b s t r a c t 2-(Trimethylsilyl)ethanesulfonyl amide (SES-NH 2 ) is an ammonia equivalent for the palladium-catalyzed amination of aryl bromides and aryl chlorides. Using these amine derivatives, it has been observed that anilines and anilines with sensitive fun