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An Alternative to Automatic Titration

โœ Scribed by Ernst Schumacher; Peter Ryser; Wolfgang Thormann


Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
224 KB
Volume
60
Category
Article
ISSN
0018-019X

No coin nor oath required. For personal study only.

โœฆ Synopsis


Abstract

Automatic titrators are designed to do exactly what a labโ€technician used to do. Much more sophisticated automation of volumetry is possible. Omegaphoresis [3] in bufferโ€free [2] sample solutions automatically creates a stationary multiple component titration curve or zoned pattern with normalized concentrations of each separated species. An automatic measurement of each zone length yields their quantity. Simultaneous automatic detection of all the zones in a 10โ€“20 component solution in less than 2 minutes, with a precision of ยฑ2%, a required amount of the order of less than one nanomol and a resolution of ยฑpK < 0.01 replaces acidโ€base, complexometric, and certain types of redoxโ€titrimetry. An option of the method allows identification of the components as well.


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