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An alternative synthesis of (+)-sesbanimide A

โœ Scribed by W. J. Vloon; J. C. van Den Bos; N. P. Willard; G.-J. Koomen; U. K. Pandit

Book ID
104589361
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
649 KB
Volume
110
Category
Article
ISSN
0165-0513

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Natural (+)-sesbanimide A (l) and (-)-sesbanimide B ($, potent antitumor alkaloids, were efficiently synthesized from the (-)-glutarimide diol ($, corresponding to the AB-ring system of l and &, which had already been derived from readily available D-xylose. Our total synthesis obviously established