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An alternative approach to amino porphyrins

✍ Scribed by Shi Weimin; Shen Qi; Wang Yucheng; Lan Lihong; Tao Jingchao

Publisher: Journal of Heterocyclic Chemistry
Year: 2010
Tongue: English
Weight: 118 KB
Volume: 47
Category: Article
ISSN: 0022-152X
DOI: 10.1002/jhet.410

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✦ Synopsis

Abstract

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Modified nitration of tetraphenylporphyrin at para of phenyl with HNO~3~/Cl~3~CCOOH and one‐pot nitration of free tetraarylporphyrins to metalized 2‐nitroporphyrin in high yield are described. A novel reducer of Zn/HCOONH~4~ has been developed for above nitro of porphyrin into amino effectively. J. Heterocyclic Chem., (2010).

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