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An additivity relation for vicinal carbon-proton spin-spin coupling constants in aliphatic compounds (Preliminary communication)

✍ Scribed by Tom Spoormaker; Marius J. A. de Bie

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
505 KB
Volume
98
Category
Article
ISSN
0165-0513

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The effect of γ-substituents on the vici
The effect of γ-substituents on the vicinal carbon-proton spin-spin coupling constants in aliphatic compounds
✍ Tom Spoormaker; Jan W. Zwikker; Marius J. A. de Bie 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 152 KB

## Abstract The increments in ^3^__J__(CH) for substituents attached to C^γ^ in the ^13^C^α^‐C^β^‐C^γ^‐^1^H coupling pathway, with respect to ^3^__J__(CH) in propane are calculated for equal C^β^‐C^γ^ rotamer population from ^3^__J__(CH) observed in the corresponding neopentyl compounds. From th