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An Active, General, and Long-Lived Palladium Catalyst for Cross-Couplings of Deactivated (Hetero)aryl Chlorides and Bromides with Arylboronic Acids

โœ Scribed by Hoshi, Takashi; Honma, Tomonobu; Mori, Ayako; Konishi, Maki; Sato, Tsutomu; Hagiwara, Hisahiro; Suzuki, Toshio


Book ID
121397050
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
610 KB
Volume
78
Category
Article
ISSN
0022-3263

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Pd/P(i-BuNCH2CH2)3N: an efficient cataly
โœ Sameer Urgaonkar; M. Nagarajan; J.G. Verkade ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

Pd(OAc) 2 in combination with the commercially available ligand P(i-BuNCH 2 CH 2 ) 3 N catalyzes the Suzuki cross-coupling reaction of a wide variety of aryl bromides and chlorides with arylboronic acids, affording the desired biaryls in excellent yields. It has also been shown that P(NMe 2 ) 3 can