✦ LIBER ✦

An account of the propagating species in cationic polymerisations

✍ Scribed by Peter H. Plesch

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 178 KB
Volume: 25
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(89)90057-8

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✦ Synopsis

The different types of cations, anions, and other species likely to be involved in the cationoid polymerisations of alkenes are discussed, with special reference to their relative abundance under different conditions.

In the context of this celebration which is dedicated to a distinguished radical monger, it may be useful to outline the intellectual plight of the cation mongers who are concerned with the polymerisations of alkenes. The essential features of radical chemistry seem to be determined principally by the relative strengths of chemical bonds and the activation energies of their rupture, with electrostatic effects, especially solvation energies, playing at most a secondary role.

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