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Ammoximation of cyclohexanone over a titanium silicate molecular sieve, TS-2

โœ Scribed by J.Sudhakar Reddy; S. Sivasanker; P. Ratnasamy


Publisher
Elsevier Science
Year
1991
Weight
552 KB
Volume
69
Category
Article
ISSN
0304-5102

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๐Ÿ“œ SIMILAR VOLUMES


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The liquid phase ammoximation of cyclohexanone, ortho and para-hydroxyacetophenones (2-HAP and 4-HAP) with ammonia and hydrogen peroxide was investigated over titanium-silicalite-1 (TS-1), titanium-aluminum-beta (Ti-A1-Beta) and Ti-ZSM-48. The ammoximation of 4-HAP over TS-1 gave the corresponding o

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The oxidation of propylamine to propionaldehyde oxime with 30 wt.-% hydrogen peroxide has been studied over the following catalysts: TS-1, TS-2, Ti-fl, Ti-MCM-41, Ti-HMS, amorphous SiO2-TiO2 and AI-/3. Only TS-I, TS-2 and Ti-/3 were found to be active in this reaction. All other catalysts were almos