Ammonolysis of waste 1,2,3-trichloropropane by liquid ammonia

✍ Scribed by Eugeniusz Milchert

• Book ID: 101265313
• Publisher: Wiley (John Wiley & Sons)
• Year: 2000
• Tongue: English
• Weight: 154 KB
• Volume: 75
• Category: Article
• ISSN: 0268-2575
• DOI: 10.1002/(sici)1097-4660(200004)75:4<320::aid-jctb222>3.0.co;2-a

✦ Synopsis

The preparation of 2-chloroallyamine by ammonolysis of 1,2,3-trichloropropane using liquid ammonia, has been examined. The in¯uence of essential parameters on the selectivity of this transformation to 2-chloroallylamine in relation to the 1,2,3-trichloropropane consumed, and to the conversion of 1,2,3-trichloropropane, have been described by regression equations in the form of a polynomial of the second order. Optimum values of temperature, reaction time and molar ratio NH 3 to 1,2,3-trichloropropane have been determined.