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Ammonolysis of Trichlorosilanes

✍ Scribed by Carsten Ackerhans; Bodo Räke; Ralph Krätzner; Peter Müller; Herbert W. Roesky; Isabel Usón

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 273 KB
Volume: 2000
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(200005)2000:5<827::aid-ejic827>3.0.co;2-j

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✦ Synopsis

The ammonolysis of trichlorosilanes RSiCl 3 [R = CH(SiMe 3 ) 2 (1a), Ph (1b), Et (1c)] leads to a series of condensed products such as six-membered rings [(Me 3 Si) 2 CHSi(OH)NH] 3 (2a) and [PhSi(NH 2 )NH] 3 (2b), disilazane [(Me 3 Si) 2 CHSi-(NH 2 ) 2 ] 2 NH (3) and the cage compound (EtSi) 6 (NH) 9 (4). The

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