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Ammonium metavanadate/thiocyanate-triggered electrophilic thiocyanation of aromatic and heteroaromatic compounds in aqueous bisulfate and acetonitrile media

โœ Scribed by Venkatesham, N.; Rajendar Reddy, K.; Rajanna, K. C.; Veerasomaiah, P.


Book ID
126649983
Publisher
Taylor and Francis Group
Year
2014
Tongue
English
Weight
186 KB
Volume
35
Category
Article
ISSN
1741-5993

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Two simple, mild, and efficient procedures for the thiocyanation of N-heterocycles, substituted anilines (electron-rich and electron-deficient), and N-substituted aromatic amines at room temperature are reported (Table 3). The first uses H 2 O 2 as pollution-free oxidant and the second H 5 IO 6 ; bo