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Ammonia-fed solid oxide fuel cells for power generation—A review

✍ Scribed by Meng Ni; Michael K. H. Leung; Dennis Y. C. Leung


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
385 KB
Volume
33
Category
Article
ISSN
0363-907X

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✦ Synopsis


Ammonia has been identified as a promising sustainable fuel and hydrogen source for solid oxide fuel cells (SOFC). This paper aims to provide a literature review on ammonia-fed SOFCs. Both experimental studies and mathematical modeling investigations on NH 3 -fed SOFC are included and discussed. It is found that NH 3 is a technically feasible fuel for direct use in SOFCs and the performance of NH 3 -fed SOFC is comparable with that of the H 2 fed SOFC. Experimental study in literature also demonstrates that both oxygen ion-conducting electrolyte (SOFC-O) and protonconducting electrolyte (SOFC-H) can be used in NH 3 -fed SOFC, as the amount of NO x generated in a SOFC-O is negligible. Fabricating thin film electrolyte and developing more reactive electrode materials are important to improve the performance of NH 3 -fed SOFCs. Mathematical models are useful design tools for understanding the coupled transport and reaction phenomena and for optimizing the SOFC performance. Thermodynamic and pioneering 1D electrochemical models have been developed, validated and demonstrated to be reliable by the present author.


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