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Amino, Azido, Azo and Nitro 4′-Substituted 2,2′: 6′,2′′- Terpyridines; Synthesis and Metal Complexes

✍ Scribed by Reza-Ali Fallahpour

Publisher
John Wiley and Sons
Year
2003
Weight
51 KB
Volume
34
Category
Article
ISSN
0931-7597

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The new ligands 4Ј-nitro-2,2Ј:6Ј,2ЈЈ-terpyridine and 4Ј-prepared and the electrochemistry of the complexes has been investigated. amino-2,2Ј:6Ј,2ЈЈ-terpyridine and their homoleptic and heteroleptic iron(II) and ruthenium(II) complexes have been 2,2Ј:6Ј,2ЈЈ-Terpyridine (tpy) is a versatile ligand for

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Novel Synthesis of Substituted 4'-Hydroxy-2,2':6',2"-terpyridines. -The Kroehnke-methodology is applied to diacetylpyridine (II). Thus the terpyridines (V), (VII), and (IX) are synthesized with substituents at C-4, C-5 and C-6 of both terminal pyridines while the 4'-position is functionalized as a