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Amino Acid-Derived Iodobenzene Dicarboxylates: Reagents for Oxidative Conversion of Alkenes to Amino Acid Esters.

✍ Scribed by Alexey Y. Koposov; Vyacheslav V. Boyarskikh; Viktor V. Zhdankin

Publisher: John Wiley and Sons
Year: 2005
Weight: 19 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200504196

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✦ Synopsis

Amino Acid-Derived Iodobenzene Dicarboxylates: Reagents for Oxidative Conversion of Alkenes to Amino Acid Esters. -The preparation of new, chiral iodobenzenecarboxylates derived from natural L-amino acids is presented. The usefulness of thus obtained (III) is shown in the reaction with tetrahydropyran (IV) affording the enantiopure amino acid esters (V) and (VI). The similar reaction of (III) with cyclohexene leads to the inseparable 1:1 mixture of diastereomeric amino acid esters. -(KOPOSOV, A.

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