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Aminium salts-induced dimerization of α-methylstyrene and 1-aryl-1-phenylethylenes. Solvent effect

✍ Scribed by Francesco Ciminale; Liugi Lopez; Vincenza Paradiso; Angelo Nacci

Book ID
103399424
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
582 KB
Volume
52
Category
Article
ISSN
0040-4020

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Acid Catalysis in the Aminium Hexachloro
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The aminium hexachloroantimonate-induced cyclodimerization of various 1-aryl-1-phenylethylenes, affording regioisomeric indane derivatives via a carbocation mechanism, was found to occur in a similar manner when SbCl 5 was used instead of the aminium salt, hence antimony pentachloride is proposed as