Kinetic studies established that the monomethylation of a primary amine leads to significantly higher reaction rates with glycidyl ethers. The relative rates for approximately 25 amines were determined in an alcohol solvent under pseudo-firstorder conditions (excess epoxy). The rates were referenced
โฆ LIBER โฆ
Amine Haloboranes. The Reaction of N-Halosuccinimide with Amine Boranes
โ Scribed by Douglass, James E.
- Book ID
- 120246585
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 256 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0022-3263
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Ammonia borane and primary amine boranes are highly chemoselective reducing agents for aldehydes and ketones. There has been much recent interest in the development of chemoselective1s2 reducing agents capable of distinguishing aldehyde and ketone functionality in a predictable manner. 'a-si While a