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Amine Exchange Reactions of Mannich Bases

โœ Scribed by Snyder, H. R.; Brewster, James H.


Book ID
115511224
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
351 KB
Volume
70
Category
Article
ISSN
0002-7863

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Amine-catalyzed direct asymmetric Mannic
โœ Wolfgang Notz; Kandasamy Sakthivel; Tommy Bui; Guofu Zhong; Carlos F Barbas III ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 82 KB

Three chiral cyclic secondary amines are shown to be catalysts for the direct asymmetric Mannich-type reaction of acetone with a variety of preformed aldimines derived from o-anisidine. A simple one-pot three-component reaction procedure consisting of aldehyde, acetone, p-anisidine and an amine cata