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Amine-Controlled Assembly of Metal—Sulfite Architecture from 1D Chains to 3D Framework.

✍ Scribed by Cristina Austria; Jian Zhang; Henry Valle; Qichun Zhang; Emily Chew; Dan-Tam Nguyen; J. Y. Gu; Pingyun Feng; Xianhui Bu

Publisher: John Wiley and Sons
Year: 2007
Weight: 24 KB
Volume: 38
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200743002

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## Abstract Hydrothermal reactions of CdCl~2~·2.5H~2~O or ZnCl~2~, sodium dicyanamide, and sodium azide yield two interesting photoluminescent coordination polymers, namely, [Cd{Cd~3~(μ~3~‐OH)(dcadtzH)~3~(H~2~O)~6~}~2~] (1) and [Zn~5~(μ~3~‐OH)~2~(μ‐OH)~2~(dcadtz)~2~]·2H~2~O (2) [dcadtzH~3~ = bis(5‐