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Amine-catalyzed decarboxylation of acetoacetic acid. The rate constant for decarboxylation of a .beta.-imino acid

โœ Scribed by Guthrie, J. Peter; Jordan, Frank

Book ID
111923088
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
724 KB
Volume
94
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

Uncatalyzed and Amine Catalyzed Decarbox
Uncatalyzed and Amine Catalyzed Decarboxylation of Acetoacetic Acid: An Examination in Terms of No Barrier Theory
โœ J.Peter Guthrie ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 101 KB

Rate constants for decarboxylation of acetoacetic acid, its anion, and its imine with aminoacetonitrile have been calculated from equilibrium constants and distortion energies using No Barrier Theory. The mechanisms of decarboxylation of both acetoacetic acid and its imine involve preequilibrium for