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Amine-Catalyzed Coupling of Allenic Esters to α,β-Unsaturated Carbonyls.

✍ Scribed by Catherine A. Evans; Scott J. Miller


Publisher
John Wiley and Sons
Year
2004
Weight
235 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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✍ Gui-Ling Zhao; Ismail Ibrahem; Henrik Sundén; Armando Córdova 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 260 KB 👁 1 views

## Abstract The direct organocatalytic enantioselective epoxidation of α,β‐unsaturated aldehydes with different peroxides is presented. Proline, chiral pyrrolidine derivatives, and amino acid‐derived imidazolidinones catalyze the asymmetric epoxidation of α,β‐unsaturated aldehydes. In particular, p