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Amine boranes as alternative reducing agents for reductive alkylation of proteins

✍ Scribed by Judy C. Cabacungan; Ahmed I. Ahmed; Robert E. Feeney

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 570 KB
Volume: 124
Category: Article
ISSN: 0003-2697
DOI: 10.1016/0003-2697(82)90038-0

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✦ Synopsis

The use of several commercially available amine-borane complexes was investigated for the reductive methylation of amino groups of several proteins. An earlier study in our laboratory, using turkey ovomucoid as the model protein, showed that dimethylamine borane is a slightly weaker reducing agent, but a good, less toxic substitute for sodium cyanoborohydride (K. F.

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