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Amination of Haloaromatics with Trichloramine-Aluminum Chloride. σ Substitution and Nucleophilic σ Substitution 1,2

✍ Scribed by Kovacic, Peter; Gormish, Joseph F.


Book ID
126259372
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
819 KB
Volume
88
Category
Article
ISSN
0002-7863

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Aromatic nucleophilic substitution VIII.
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Ever since Servis' first observed by NMR spectrometry that in DMSO much faster formation of 1,3\_disubstituted anionic o complex (hereinafter referred to as 1,3-adduct) from 2,4,6\_trinitroanisole (TNA) and 'OCH3 is followed by a much slower attack on the l-position, considerable attention has been