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Amidrazones. 8. Synthesis of 1,2,4-oxdiazoles by thermolysis of N3-acylamidrazone ylides

✍ Scribed by Richard F. Smith; Karen J. Coffman; Susan M. Geer


Book ID
112126984
Publisher
Journal of Heterocyclic Chemistry
Year
1983
Tongue
English
Weight
173 KB
Volume
20
Category
Article
ISSN
0022-152X

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Thermolysis of 1-homcadamantyl hypoicdite followed by intramolecular cyclization yields 74% of the hitherto unknown lo-homcprctoadamantan-4-one; the hypoicdite thermolysis-cyclizatien sequence appears to be an excellent method for the preparation of adamantanoid ketones. ~3 -Scission of tertiary po